FORMATION OF DEOXYBENZOINS FROM 1,3-DIMETHYL-2-(α-BENZYLOXYBENZYL)BENZIMIDAZOLIUM IODIDES THROUGH REARRANGEMENT FOLLOWED BY EXPULSION OF AZOLIUM YLIDE
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概要
- 論文の詳細を見る
Treatment of several 1,3-dimethyl-2-(α-benzyloxybenzyl)benzimidazolium iodides 1 with K_2CO_3 gave deoxybenzoins 2 in moderate yields. Deoxybenzoins 2 were produced through rearrangement of benzyl groups followed by expulsion of 1,3-dimethylbenzimidazolium ylide (4). The reaction is classified as a Witting rearrangement.
- 公益社団法人日本薬学会の論文
- 1994-09-15
著者
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東野 武郎
School Of Pharmaceutical Sciences University Of Shizuoka
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岩本 憲人
School of Pharmaceutical Sciences, University of Shizuoka
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宮下 晶
School Of Pharmaceutical Sciences University Of Shizuoka
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岩本 憲人
静岡県立大学薬学部
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松岡 芳幸
School of Pharmaceutical Sciences, University of Shizuoka
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松岡 芳幸
School Of Pharmaceutical Sciences University Of Shizuoka
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Iwamoto K
Eisai Co. Ltd. Gifu Jpn
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