TRIETHYLSILYLATION OF HYDROXYL GROUPS WITH A KETENE TRIETHYLSILYL ACETAL 2-METHYL-1-TRIETHYLSILYLOXY-1-METHOXYPROPENE
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概要
- 論文の詳細を見る
A convenient O-triethylsilylation with dimethylketene triethylsilyl methyl acetal (1), which is prepared in excellent yield by catalytic hydrosilylation of methyl metacrylate is reported. Primary alcohols react readily at room temperature. Hindered alcohols are rapidly silylated in the presence of a trace amount of trifluoromethanesulfonic acid. For phenols heating with or without solvent is required.
- 公益社団法人日本薬学会の論文
- 1983-12-25
著者
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武田 敬
富山医薬大・薬
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武田 敬
Faculty Of Pharmaceutical Sciences University Of Tokyo
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吉井 英一
Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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吉井 英一
富山医科薬科大学薬学部
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