Sulfoxonium Ylide Chemistry. III. The Photochemistry of Stable Sulfoxonium Ylides
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概要
- 論文の詳細を見る
Photochemical reaction of dimethylsufoxonium 3-ethoxycarbonyl-2-phenylallylide (I) gave diethyl p-terphenyl-2', 5'-dicarboxylate (II) in low yield. Irradiation of dimethylsulfoxonium 1,2-dicarbomethoxy-5-carbethoxy-4-phenyl-1,4-pentadien-3-ylide (VI) with an ultraviolet lamp afforded three products, 3-carbethoxy-1,2-dicarbomethoxy-4-methylnaphthalene (VII) (37.5% yield), dimethyl 3-oxo-1,3-dihydronaphtho [1,2-c] furan-4,5-dicarboxylate (VIII) (0.39% yield) and dimethyl 3-oxo-1,3,4,5-tetrahydronaphtho [1,2-c]-furan-4,5-dicarboxylate (IX) (0.35% yield).
- 公益社団法人日本薬学会の論文
- 1969-08-25
著者
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岸田 有吉
Central Research Laboratories Sankyo Co. Ltd.
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平岡 哲夫
Central Research Laboratories, Sankyo Co., Ltd.
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井手 純也
Central Research Laboratories, Sankyo Co., Ltd.
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井手 純也
Sankyo Research Laboratories, Sankyo Co., Ltd.,
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井手 純也
Sankyo Research Laboratories Sankyo Co. Ltd.
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平岡 哲夫
三共(株)総合研究所
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