Studies on Acetylenic Compounds. XL. The Addition Reaction of Nitrosyl Chloride and Nitryl Chloride to Acetylenic Compounds
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概要
- 論文の詳細を見る
The addition reaction of nitryl chloride and nitrosyl chloride with phenyl acetylene (Ia), phenylmethylacetylene (Ib), diphenylacetylene (Ic), 3-phenyl-2-propyn-1-ol alcohol acetate (Id), phenylpropiolic acid (Ie), and ethyl phenylpropiolate (If) was carried out under various conditions which afforded the corresponding chloro-nitroolefins : α-chloro-β-nitrostyrene (trans IIa and cis IIa), 1-chloro-1-phenyl-2-nitro-1-propene-1(IIb), α-chloro-β-nitrostylbene(IIc), 2-nitro-3-chloro-3-phenyl-2-propen-1-ol acetate (IId), α-nitro-β-chlorocinnamic acid (IIe), and ethyl α-nitro-β-chlorocinnamate (IIf) respectively. The geometrical relationship of the isomers of α-chloro-β-nitrostyrene were determined by dipole moments and infrared and ultraviolet spectra.
- 公益社団法人日本薬学会の論文
- 1965-02-25
著者
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岩井 一成
Central Research Laboratories, Sankyo Co., Ltd.
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富田 和男
Agricultural Chemicals Research Laboratories Sankyo Co. Ltd.
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岩井 一成
Research Laboratories, Sankyo Co., Ltd.
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富田 和男
Research Laboratories, Sankyo Co., Ltd.
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井手 純也
Research Laboratories, Sankyo Co., Ltd.
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井手 純也
Sankyo Research Laboratories, Sankyo Co., Ltd.,
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井手 純也
Sankyo Research Laboratories Sankyo Co. Ltd.
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岩井 一成
Central Research Laboratories Sankyo Co. Ltd.
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