Studies on Acetylenic Compounds. XV. Synthesis of 16-Ethynylated Steroids.
スポンサーリンク
概要
- 論文の詳細を見る
3β, 17β-Diacetoxyandrost-5-en-16-one and 3β-methoxy-17β-acetoxyandrost-5-en-16-one were ethynylated with lithium acetylide. The resulting 16α-ethynyl-16β, 17β-diol afforded 16,17-acetonide on treating with acetone, one of which was converted into 16α-ethynyl-16β, 17β-dihydroxyandrost-4-en-3-one by Oppenauer oxidation of the corresponding 3-ol and hydrolysis of 16,17-acetonide.
- 公益社団法人日本薬学会の論文
- 1960-09-25
著者
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岩井 一成
Takamine Laboratory, Sankyo Co., Ltd.
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平岡 哲夫
Takamine Research Laboratory, Sankyo Co., Ltd.
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平岡 哲夫
三共(株)総合研究所
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岩井 一成
Central Research Laboratories Sankyo Co. Ltd.
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