Studies on Acetylenic Compounds. LVIII. Reaction of 2-Propynyl Sulfones with Methyl Acrylate
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概要
- 論文の詳細を見る
Three 2-propynyl sulfones (VIIIa-c) reacted with methyl acrylate to give the corresponding 2-carbomethoxy-4-ethynyl-4-arylsulfonylcyclohexanones (IXa-c), respectively. Nucleophilic reaction of acetylenic sulfonyl carbanion showed ambident character depending on the nature of electrophiles which were classified into two kinds. Some discussions of the reaction and physical properties of the products are presented.
- 公益社団法人日本薬学会の論文
- 1972-10-25
著者
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吉本 昌文
Central Research Laboratories, Sankyo Co., Ltd.
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岸田 有吉
Central Research Laboratories Sankyo Co. Ltd.
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石田 登
New Lead Research Laboratories, Sankyo Co., Ltd.,
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石田 登
Central Research Laboratories, Sankyo Co., Ltd.
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石田 登
New Lead Research Laboratories Sankyo Co. Ltd.
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吉本 昌文
Department Of Chemistry Pomona College
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