Valence-Band X-Ray Photoemission of PbI_2 and CdI_2
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概要
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The valence-band spectrum in X-ray photoemission of PbI_2 does not agree with the reported results of energy-bend calculations, which predict that the highest valence band vonsists mainly of the 6s state of Pd^<++> and is isolated from other component-bands. Weak lines are found about 6 eV below the valence-band lines in various Pb-compounds. It is suggested that either the weak line in PbI_2 corresponds to the 6s level of Pd^<++> or the upper part of the valence band has both the 6s character of Pd^<++> and the 5p character of I^-appreciably. The valence-band spectrum of CdI_2 resembles the valence-band spectrum of PbI_2. The data of the chlorides and bromides of Pb and Cd are also presented.
- 社団法人日本物理学会の論文
- 1976-10-15
著者
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Ishii Takehiko
Department Of Material Physics Graduate School Of Engineering Science Osaka University
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Ishii Takehiko
Department Of Physics Tohoku University:institute For Solid State Physics University Of Tokyo
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Matsukawa Tokuo
College Of General Education Osaka University
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