<報文>ゼオライトによるCsとSrの分離

概要

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The basic studies of separation of cesium and strontium were made with specimens of zeolite, which are synthetic zeolites A, X and Y ; synthetic mordenite ; natural mordenite ; and clinoptilolite. Ammonium chloride was used as eluent, because it was considered to be a most appropriate eluent in alkaline chlorides. Cesium was easily eluted from the zeolites A and X by ammonium chloride solution, but it was difficult to elute from the synthetic mordenite, natural mordenite and clinoptilolite. On the contrary, strontium was easily eluted from the synthetic mordenite, natural mordenite and clinoptilolite by ammonium chloride solution, but it was difficult to elute from the zeolites A and X. The zeolite Y is the only one zeolite among these zeolites from which both of cesium and strontium were easily eluted by ammonium chloride solution Strontium could be separated from cesium with zeolites by formation of Sr-EDTA chelate at pH above 11. In this process, cesium was only exchanged in zeolite column, but strontium flow out from it.
東北大学の論文
1976-09-30