金属カルボニルを用いる高選択的反応の開発と生物活性物質合成への応用
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概要
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Alkynes react with commercially available Co2(CO)8 to give the corresponding alkyne-Co2(CO)6 complexes. Similarly, treatment of arenes with Cr(CO)6 produces arene-Cr(CO)3 complexes. By taking advantage of the intriguing properties of these metal carbonyl complexes, we developed some selective reactions. In this review, the following topics are discussed: (i) development of selective reactions based on alkyne-Co2(CO)6 complexes; (ii) development of selective reactions based on arene-Cr(CO)3 complexes; and (iii) their application to syntheses of bioactive compounds.
- 社団法人 日本薬学会の論文
- 2002-11-01
著者
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