Structural and Optical Properties of Phthalocyanine Thin Films Grown on Glass with 3,4,9,10-Perylene Tetracarboxylic Dianhydride Intermediate Layer
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概要
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The molecular orientation and optical properties of phthalocyanine (H2Pc) films grown on glass with a 3,4,9,10-perylene tetracarboxylic dianhydride (PTCDA) intermediate layer were investigated by infrared reflection absorption spectroscopy and absorption spectrum analysis. The orientation of the H2Pc molecular plane became almost parallel to the substrate surface with the introduction of a thin PTCDA layer on a glass substrate during initial growth. However, the orientation of the H2Pc molecular plane turned from parallel to oblique with increasing layer thickness, and finally the angle approached 26.5°, which indicates the formation of a crystalline phase of $\alpha$-H2Pc with the $b$-axis perpendicular to the substrate surface. The optical absorption of the film was significantly affected by the molecular arrangement, and the importance of molecular orientation control was suggested.
- Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
- 2006-01-15
著者
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Akimoto Katsuhiro
Institute Of Applied Physics University Of Tsukuba
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Kawai Shunsuke
Institute Of Applied Physics University Of Tsukuba
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Sakurai Takeaki
Institute Of Applied Physics University Of Tsukuba
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Fukasawa Ryosuke
Institute Of Applied Physics University Of Tsukuba
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Fukasawa Ryosuke
Institute of Applied Physics, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan
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Kawai Shunsuke
Institute of Applied Physics, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan
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