Radiation-induced alkylation, hydroxyalkylation, and reduction of pyridinecarboxamides in acidic alcoholic solutions.
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概要
- 論文の詳細を見る
The γ-irradiation of pyridinecarboxamides in acidic methanol or ethanol brings about substitution of the ring hydrogen by alkyl or hydroxyalkyl groups derived from the solvent alcohols in relatively high <I>G</I>-values. In 2-propanol, little alkylation and hydroxyalkylation occur and reduction of CONH<SUB>2</SUB> to CH<SUB>2</SUB>OH occurs in low <I>G</I>-values.
- 公益社団法人 日本化学会の論文
著者
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Sugimori Akira
Department Of Chemistry Faculty Of Science And Technology Sophia University
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Itoh Hiroshi
Department Of Advanced Materials Science Faculty Of Engineering Kagawa University
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Nishijima Masayuki
Department of Chemistry, Faculty of Science and Technology, Sophia University
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