Substituent effects on the photo-ethoxycarbonylation of monosubstituted ferrocenes.
スポンサーリンク
概要
- 論文の詳細を見る
The effect of the substituent in the ferrocene nucleus on the photo-ethoxycarbonylation of monosubstituted ferrocene in carbon tetrachloride–ethanol solution is described. The electron withdrawing substituents, such as chloro, bromo, iodo, cyano, and acetyl, retarded the photo-ethyoxycarbonylation, whereas the electron releasing substituents, such as ethyl accelerated the reaction. The electronic effects which affect the formation of the charge transfer complex and those which affect the reactivity of the cyclopentadienyl ring toward the attack of a trichloromethyl radical can be considered for the photo-ethoxycarbonylation.
- 公益社団法人 日本化学会の論文
著者
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Kato Takao
Department of Cardiology, Graduate School of Medicine, Kyoto University
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Kitamura Taro
Department Of Pediatrics Tohoku University School Of Medicine
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Sugimori Akira
Department Of Chemistry Faculty Of Science And Technology Sophia University
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Akiyama Takeo
Department Of Chemistry Faculty Of Science And Technology Sophia University
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Watanabe Haruo
Department Of Bacteriology I National Institute Of Infectious Diseases
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Serizawa Toshio
Department of Chemistry, Faculty of Science and Technology, Sophia University
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Watanabe Haruo
Department of Chemistry, Faculty of Science and Technology, Sophia University
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Kato Takao
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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Kato Takao
Department of Chemistry, Faculty of Science and Technology, Sophia University
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