Photochemical ligand substitution in hexakis(aryl isocyanide)-chromium(O)-olefin systems.
スポンサーリンク
概要
- 論文の詳細を見る
Isocyanide chromium(0) complexes coordinated by dimethyl fumarate, fumaronitrile and maleic anhydride were prepared photochemically by the irradiation of hexakis(aryl isocyanide)chromium(0) with the corresponding olefin. Tetracyanoethylene reacts with hexakis(aryl isocyanide)chromium(0) thermally without illumination, while acrylonitrile and dimethyl maleate do not react even with irradiation.
- 公益社団法人 日本化学会の論文
著者
-
Sugimori Akira
Department Of Chemistry Faculty Of Science And Technology Sophia University
-
Kinugasa Takashi
Department of Chemistry, Faculty of Science and Technology, Sophia University
-
Iuchi Kazuhito
Department of Chemistry, Faculty of Science and Technology, Sophia University
-
Asada Shintaro
Department of Chemistry, Faculty of Science and Technology, Sophia University
-
Kanamori Koji
Department of Chemistry, Faculty of Science and Technology, Sophia University
関連論文
- Cleavage of Co-C Bond in a Cobaltathiirane by Hydrogen Chloride and Reformation of Co-C Bond by Tetrabutylammonium Fluoride
- Crystal Structure of [Bis(1, 2-diphenylphosphino)ethane] (maleonitriledithiolato)-nickel(II) [Ni(dppe)(mnt)]・CH_2Cl_2
- Crystal Structure of Scandium Complex of 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone
- Oxygen-Dependent Photoreactions of 3-Substituted N-Methylpyridinium in Methanol
- Synthesis and Chemical Properties of Metalladithiolene and Metalladithiazole Rings. Unique Reactions Due to Coexistence of Aromaticity and Unsaturation
- (η^5-Cyclopentadienyl)(Halo or Acido)(Substituted 1-Methylthio-χS-ethylene-2-thiolato)cobalt(III) : Formaton, Stereoisomers, and Isomerization
- Thermal and Photochemical Formation of Dinuclear Molybdenadithiolene Complexes in One-Pot Reactions among [(Cp)_2Mo_2(CO)_6], Elemental Sulfur and Dimethyl Acetylenedicarboxylate
- Formation of Cobaltadithiolene in a One-Pot Reaction among[Co(Cp)(CO)_2], α, β-Unsaturated Carbonyls, and Elemental Sulfur
- Reaction of 5-Phenyl-3H-1, 2-dithiol-3-one and Thione with [Rh (Cp^*) (CO)_2]・Formation of Metalladithiolene Rings via Rearrangement
- Reaction of [Co(η^5-Cp)I(S_2CNMe_2)] with Diazomethane - Formation and Structures of 5-Membered 1,2,4-Cobaltadithiolene by Insertion of Methylene and 4-Membered 1,3-Cobaltathietane Formed by Desulfurization and Insertion of Methylene
- Reactions of Aryl Azides with Cobaltadithiolenes. Substitution Reactions via Nitrene
- Formation and Photochemical and Thermal Reactions of Adduct between 1,2,5,3-Cobaltadithiazole and Dimethyl Acetylenedicarboxylate
- Formation of (η^5-Pentamethylcyclopentadienyl)(1-phenylmethanimine-N, 1-dithiolato)cobalt(III) Having a Novel Metallacycle, 1, 2, 5, 3-Cobaltadithiazole, in Reactions of [Co(cp^*)(CO)2] with Heterocyclic Compounds Containing S and N
- Ionic and Radical Substitution in Cobaltadithiolene Ring Induced by Dibenzoyl Peroxide
- Reactions of Tetracyanoethylene Oxide(TCNEO)with Cobaltadithiolene Complexes
- Photochemistry of metalladichalcogenolene complexes
- Photoreaction of ferrocene with some acetylene derivatives.
- Effects of Solvents and Added Amines on the Selective Hydrogenation of 2-Naphthol over Urushibara Nickel and Cobalt Catalysts
- Unusually high oxidation half-wave potentials of di- and trichalcogena(3)ferrocenophanes. The effect of chalcogen atoms in the bridge.
- Change of orientation in photoreaction by oxygen. Effect of oxygen on photo-methoxylation of dimethyl esters of 2,4- and 3,4-pyridinedicarboxylic acid.
- Formation of (.ETA.-cyclopentadienyl)(1,2-ethylenedithiolato, 1,2-ethylenediselenolato, and 2-selenolatoethylenethiolato-S,Se) cobalt(III) complexes in a one-pot-reaction of (.ETA.-cyclopentadienyl)(1,5-cyclooctadiene or dicarbonyl)cobalt(I) with alkyne a
- Photocatalytic behavior of di- and triferrocenylbenzenes on reduction of methyl viologen and photochemical hydrogen evolution from methanol under visible light.
- Photo-ethoxycarbonylation of Anisole, Dimethylaniline and Thiophene in Carbon Tetrachloride–Ethanol Solutions
- A route from 1,1,1,3-tetrachloro-3-phenylpropane to ethynyl phenyl ketone involving elimination of hydrogen chloride and 1,3-proton transfer.
- Multiple paths for photo-methylation and -methoxylation of methyl 2-pyridinecarboxylate in methanol.
- Radiation-induced reactions of pyridinecarboxylic esters in acidic alcoholic solutions. Substitution by alkyl and hydroxyalkyl groups and reduction of carboxylic esters to alcohol.
- Effects of additives on photo-methoxylation of methyl 2-pyridinecarboxylate in acidic methanolic solutions. Promotion by 4-substituted pyridines.
- Photoreactions of Heteroaromatic Compounds. IV. Solvent and Acidity Dependence of the Photoreactions of Nicotinic Acid and Its Derivatives
- Ultraviolet photoelectron spectra of crown ethers.
- Photochemical formation of tetrahydro-2-furyl ether in alcohol-tetrahydrofuran-iron(III) chloride system.
- Substituent effects on the photo-ethoxycarbonylation of monosubstituted ferrocenes.
- The Mechanism of Photo-substitution of Ferrocene in Haloalkane–Ethanol Solutions
- Catalytic Hydrogenation of Cyclic Olefins on Nickel Catalysts
- Photoisomerization of bis(t-butyl isocyanide)dichlorobis(triphenylphosphine)ruthenium(II).
- Photochemical ethoxycarbonylation, formylation, and ethoxymethylation of ruthenocene in ruthenocene-polychloromethane-ethanol systems.
- Photochemical Substitution of Ferrocene in Halogenated Hydrocarbon–Ethanol Solutions
- Photochemical trifluoromethylation of some aromatic and heteroaromatic compounds with trifluoromethyl bromide.
- Effects of chelated and non-chelated transition metal ions on the photoreactions of pyridinecarboxylic acids in aqueous solutions.
- Radiation-induced alkylation of quinoline derivatives with alcohol.
- Photochemical Reactions of Nicotinic Acid in Aqueous and Ethanol Solutions
- Substitution of cyano group by hydroxyalkyl group and of ring hydrogen by alkoxyl group in UV-irradiation of 2-pyridinecarbonitrile in alcohols.
- Photochemical ligand substitution in hexakis(aryl isocyanide)-chromium(O)-olefin systems.
- A comparative study of nickel and cobalt catalysts in the hydrogenation of substituted acetophenones. Dependence of hydrogenation rate and adsorption strength on substituents and solvents.
- Radiation-induced alkylation, hydroxyalkylation, and reduction of pyridinecarboxamides in acidic alcoholic solutions.
- Visible light-and radiation-induced alkylation of pyridine ring with alkanoic acid. Effective alkylation in the presence of iron(III) sulfate.