Photochemical Substitution of Ferrocene in Halogenated Hydrocarbon–Ethanol Solutions
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概要
- 論文の詳細を見る
The photochemical substitution of ferrocene in several halogenated hydrocarbon–ethanol solutions was investigated. Ethoxycarbonyl, formyl, ethoxymethyl, benzyl and allyl groups were photochemically introduced into ferrocene in 25–53% yields by the UV-irradiation of ferrocene in carbon tetrachloride–, chloroform–, dichloromethane–, benzyl chloride–, and allyl bromide–ethanol solutions, respectively. The reactions proceeded effectively by the excitation of the charge transfer complexes formed between ferrocene and halogenated hydrocarbons.
- 公益社団法人 日本化学会の論文
著者
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Sugimori Akira
Department Of Chemistry Faculty Of Science And Technology Sophia University
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Akiyama Takeo
Department Of Chemistry Faculty Of Science And Technology Sophia University
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Hoshi Yoshiyuki
Department Of Pediatrics School Of Medicine Tohoku University Hospital Tohoku University
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Goto Satoshi
Department of Chemistry, Faculty of Science and Technology, Sophia University
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