Photoreaction of ferrocene with some acetylene derivatives.
スポンサーリンク
概要
- 論文の詳細を見る
The UV-irradiation of ferrocene and dimethyl acetylenedicarboxylate in acetic acid–water solution afforded dimethyl ferrocenylmaleate and dimethyl ferrocenylfumarate in 40 and 5% yield, respectively. Methyl 3-carbamoylpropiolate, dicyanoacetylene, and methyl propiolate were also reactive and the corresponding substituted ferrocenes were obtained. The reaction can be considered to proceed <I>via</I> the excitation of the charge transfer complex between ferrocene and acetylene derivatives.
- 公益社団法人 日本化学会の論文
著者
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Sugimori Akira
Department Of Chemistry Faculty Of Science And Technology Sophia University
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Akiyama Takeo
Department Of Chemistry Faculty Of Science And Technology Sophia University
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Watanabe Haruo
Department Of Bacteriology I National Institute Of Infectious Diseases
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Ito Kazuo
Department Od Orthopedic Surgery Sapporo Medical University
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Ito Kazuo
Department of Chemistry, Faculty of Science and Technology, Sophia University
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Nakanishi Fumio
Department of Chemistry, Faculty of Science and Technology, Sophia University
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Watanabe Haruo
Department of Chemistry, Faculty of Science and Technology, Sophia University
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