Catalytic Hydrogenation of Cyclic Olefins on Nickel Catalysts
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概要
- 論文の詳細を見る
The catalytic hydrogenation of cyclic olefins was investigated over various nickel catalysts. The hydrogenation of cyclohexene was promoted by basic reaction conditions and depressed by acidic ones, the hydrogenation of cyclooctene being only slightly influenced by the acidity. The results of competitive hydrogenation indicate that cyclooctene is adsorbed more strongly on nickel catalysts than cyclohexene. The external olefinic bond is preferentially hydrogenated to the internal olefinic bond.
- 公益社団法人 日本化学会の論文
著者
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Okada Junko
Department Of Respiratory Medicine Japanese Red Cross Medical Center Tokyo
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KAJITANI Masatsugu
Department of Chemistry, Faculty of Science and Technology, Sophia University
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Sugimori Akira
Department Of Chemistry Faculty Of Science And Technology Sophia University
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Sasaki Yoshiaki
Department Of Biological Environment Faculty Of Bioresource Sciences Akita Prefectural University
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Urushibara Yoshiyuki
Department of Chemistry, Faculty of Science, The University of Tokyo
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Ohmura Kazuo
Department of Chemistry, Faculty of Science and Technology, Sophia University
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Okada Junko
Department of Chemistry, Faculty of Science and Technology, Sophia University
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Urushibara Yoshiyuki
Department of Chemistry, Faculty of Science and Technology, Sophia University
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