Acid dissociation constants of dialkyldithiocarbamic acids and O,O'-dialkyl S-hydrogen dithiophosphates and formation constants of their complexes with cadmium(II), zinc(II), and lead(II) in 1:1 v/v water-DMF medium.
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概要
- 論文の詳細を見る
The log values of β<SUB>3</SUB>, the formation constants of metal complexes with dialkyldithiocarbamates and <I>O</I>,<I>O</I>′-dialkyl dithiophosphates, were determined by polarography. The p<I>K</I><SUB>a</SUB> values, the acid-dissociation constants of these ligands, were also determined kinetically. A linear relationship exists between these two variables for each metal and straight parallel lines were obtained.
- 公益社団法人 日本化学会の論文
著者
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Tagashira Shoji
Department Of Chemistry Graduate School Of Science And Engineering Yamaguchi University
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Sasaki Yoshiaki
Department Of Biological Environment Faculty Of Bioresource Sciences Akita Prefectural University
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Yanagidani Takagimi
Department Of Mechanical Science And Engineering Tokyo Institute Of Technology
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Hayashi Kenjiro
Department of Chemistry, Faculty of Science, Yamaguchi University
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