Preferred conformations of cis-4-hydroxy-2-chromancarboxylates and related compounds. Molecular force field interpretation.
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概要
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In contrast to <I>cis</I>-4-hydroxy-2-tetralincarboxylates, <I>cis</I>-4-hydroxy-2-chromancarboxylates take diaxial conformation having 4-pseudoaxial-OH and 2-axial-COOR groups preferably. The preferred conformations of these compounds were rationalized by molecular force field (MM 1/MMP 1) calculations on the corresponding 2-tetralin- and 2-chromancarbaldehydes as model compounds.
- 公益社団法人 日本化学会の論文
著者
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Ikegami Yusaku
Chemical Research Institute Of Non-aqueous Solutions
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Muramatsu Takashi
Research Institute For Science Education Miyagi University Of Education
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Suezawa Hiroko
Deparment of Synthetic Chemistry, Division of Materials Science and Chemical Engineering, Faculty of Engineering, Yokohama National University
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Abe Kazuhisa
Department of Applied Chemistry, Faculty of Engineering, Yokohama National University
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Hirota Minoru
Deparment of Synthetic Chemistry, Division of Materials Science and Chemical Engineering, Faculty of Engineering, Yokohama National University
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Shibata Masamichi
Department of Applied Chemistry, Faculty of Engineering, Yokohama National University
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Hanaya Kaoru
Research Institute for Science Education, Miyagi University of Education
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