An anion radical precursor in the nucleophilic substitution of p-dinitrobenzene.
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概要
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Appearance of <I>p</I>-dinitrobenzene anion radical has been demonstrated by visible and ESR spectroscopy in the replacement of the one nitro group of <I>p</I>-dinitrobenzene by hydroxide ion in aqueous dimethyl sulfoxide. The formation of the anion radical seems to be due to the direct electron transfer from hydroxide ion to <I>p</I>-dinitrobenzene. The results of kinetic studies suggest that the anion radical is a precursor in the substitution reaction.
- 公益社団法人 日本化学会の論文
著者
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Ikegami Yusaku
Chemical Research Institute Of Non-aqueous Solutions
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Abe Takehiro
College of General Education, Tohoku University
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Ikegami Yusaku
Chemical Research Institute of Non-Aqueous Solutions, Tohoku University
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