Comparison of the excited-state dipole moments and polarizabilities estimated from solvent spectral shifts with those from electrooptical measurements.
スポンサーリンク
概要
- 論文の詳細を見る
On the assumption that the average energy for all transitions from a low-lying excited state to all other states was approximately the same as that for all transitions from the ground state to all excited states, Abe's improved expression for the solvent spectral frequency shift (<I>Bull. Chem. Soc. Jpn.</I>, <B>54</B>, 327 (1981)) was applied to spectral data for some neutral organic molecules in solution in order to estimate their excited-state dipole moments and polarizabilities. The changes in the dipole moments and/or polarizabilities of these molecules upon excitation were compared with those obtained from electrooptical measurements. Both methods give results that are consistent.
- 公益社団法人 日本化学会の論文
著者
-
Abe Takehiro
College of General Education, Tohoku University
-
Iweibo Idowu
College of General Education, Tohoku University
関連論文
- Blue-colored Matter Appearing in an Alkaline Solution of Benzoin and Benzil in Aqueous Dimethyl Sulfoxide
- An anion radical precursor in the nucleophilic substitution of o-dinitrobenzene.
- An anion radical precursor in the nucleophilic substitution of p-dinitrobenzene.
- Solvent effects on the n.PI.* and .PI..PI.* absorption intensities of some organic molecules.
- Comparison of the excited-state dipole moments and polarizabilities estimated from solvent spectral shifts with those from electrooptical measurements.