An Electron Spin Resonance Study of the Tropone Anion Radical
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概要
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The ESR spectrum of the tropone anion radical has been examined. The radical was generated from the neutral species by the electrolytic reduction in <I>N</I>,<I>N</I>-dimethylformamide. Splitting constants are satisfactorily explained in terms of the calculated spin densities by the McLachlan procedure, confirming that the unpaired spin orbital belongs to an <I>a</I><SUB>2</SUB> symmetrical species. The complete delocalization of the π-electrons was assumed for the anion radical.
- 公益社団法人 日本化学会の論文
著者
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Ikegami Yusaku
Chemical Research Institute Of Non-aqueous Solutions
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Seto Shuichi
Chemical Research Institute of Non-Aqueous Solutions, Tohoku University
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Seto Shuichi
Chemical Research Institue of Non-Aqueous Solutions, Tohoku University
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Watanabe Hidetoshi
Chemical Research Institute of Non-Aqueous Solutions, Tohoku University
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