ESR spectra of anion radicals of 8,8-dicyanoheptafulvene and its 4,5-benzo derivative.
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概要
- 論文の詳細を見る
The hyperfine splitting constants for the 8,8-dicyanoheptafulvene anion radical generated electrolytically at low temperature indicate that the unpaired spin belongs to an a<SUB>2</SUB> orbital of the group C<SUB>2v</SUB>. Its 4,5-benzo derivative gives a stable anion radical by reduction with alkali metals. The odd electron belongs to a b<SUB>2</SUB> orbital.
- 公益社団法人 日本化学会の論文
著者
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Ikegami Yusaku
Chemical Research Institute Of Non-aqueous Solutions
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Muramatsu Takashi
Research Institute For Science Education Miyagi University Of Education
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Asao Toyonobu
College of General Education, Tohoku University
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