Fe3O4-catalyzed halogen-exchange reactions of polyhalomethanes.
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概要
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Triiron tetraoxide pretreated by polyhalomethane was shown to catalyze the halgen-exchange reactions of polyhalomethanes CH<I><SUB>l</SUB></I>Br<I><SUB>m</SUB></I>Cl<I><SUB>n</SUB></I>(<I>l</I>=1 or 2). The exchange proceeds consecutively giving, for example, CHBrCl<SUB>2</SUB>, CHBr<SUB>2</SUB>Cl, and CHBr<SUB>3</SUB> as the main products from CHCl<SUB>3</SUB>. The mechanism of the reaction is discussed briefly.
- 公益社団法人 日本化学会の論文
著者
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Hirota Minoru
Department Of Animal Science Obihiro University Of Agriculture And Veterinary Medicine
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Nakada Masahiro
Chemical Laboratory, Chiba Institute of Technology
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Tokumoto Sei-ichi
Chemical Laboratory, Chiba Institute of Technology
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Hirota Minoru
Deparment of Synthetic Chemistry, Division of Materials Science and Chemical Engineering, Faculty of Engineering, Yokohama National University
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