On the Photochemical Hydrogen Shifts in Arylcycloheptatrienes
スポンサーリンク
概要
- 論文の詳細を見る
Photochemically-induced hydrogen shifts in 7-(<I>p</I>-chlorophenyl), 7-phenyl, 7-(<I>p</I>-methoxyphenyl) and 7-<I>p</I>-tolylcycloheptatrienes (Ia—d) were studied. The possibility of hydrogen 1,7 and 1,3 shifts in these compounds was examined on both experimental and theoretical grounds. It was concluded that the hydrogen 1,7 shift is the only suprafacial hydrogen shift possible in the excited cycloheptatriene system. In this study all the isomers of <I>p</I>-chlorophenylcycloheptatriene were separated by applying the Diels-Alder reaction to the photo-reaction mixture; the method of preparing each of those isomers will also be described.
- 公益社団法人 日本化学会の論文
著者
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Kimura Masaru
Department Of Anatcmy Aichi Medical University
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Tezuka Takahiro
Department of Chemistry Faculty of Science Tohoku University
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Mukai Toshio
Department of Chemistry, Faculty of Science, Tohoku University
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Sato Aiya
Department of Chemistry, Faculty of Science, Tohoku University
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Mukai Toshio
Department of Chemistry, Faculty of Science Tohoku University
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Tezuka Takahiro
Department of Chemistry, Faculty of Science, Tohoku University
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