Photochemical nucleophilic substitution reactions of methyl substituted derivatives of p- and o-nitroanisole.
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概要
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Photosubstitution reactions of several methyl substituted derivatives of <I>p</I>- and <I>o</I>-nitroanisole with hydroxide ion were investigated. The methyl substituent seemed to show an uncertain (probably electronic) effect in addition to the steric effect for the replacement of both the methoxy and the nitro groups. Mainly, the replacement reaction of the nitro group is discussed.
- 公益社団法人 日本化学会の論文
著者
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Mukai Toshio
Department of Chemistry, Faculty of Science, Tohoku University
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Sawaura Masaki
Department of Chemistry, Faculty of Science, Tohoku University
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