Cycloreversion reaction of cage compounds initiated by aminium cation radical salts.
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概要
- 論文の詳細を見る
Treating cage compounds <B>1</B> with triarylaminium cation radical salts, <B>3</B> and <B>4</B>, resulted in the effective conversion of <B>1</B> to dienes <B>2</B>. The cation radical isomerization induced by electron-transfer from <B>1</B> to aminium salt was suggested by the effect of substituent of <B>1</B> as well as by the effect of addition of electron donors as quenchers.
- 公益社団法人 日本化学会の論文
著者
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Hasegawa Eietsu
Department Of Applied Chemistry Faculty Of Engineering Niigata University
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Mukai Toshio
Department of Chemistry, Faculty of Science, Tohoku University
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