The Photochemical and the Thermal Reaction of Dimethyl <I>trans</I>-Spiro[2.6]nona-4,6,8-triene-1,2-dicarboxylate
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概要
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The irradiation of dimethyl <I>trans</I>-spiro[2.6]nona-4,6,8-trien-1,2-dicarboxylate (I) with a low-pressure mercury lamp afforded two tricyclic valence isomers (II and III). Upon heating, II and III were converted into dimethyl <I>trans</I>-indan-1,2-dicarboxylate (IV), which was also obtained by the thermolysis of I. In order to elucidate the reaction mechanism for the formation of IV from I, we studied the thermal reaction using a deuteriumlabelled compound (V).
- 公益社団法人 日本化学会の論文
著者
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Toda Takashi
Department Of Applied Chemistry Faculty Of Engineering Utsunomiya University
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Saito Katsuhiro
Department Of Agricultural And Resource Economics The University Of Tokyo
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Mukai Toshio
Department of Chemistry, Faculty of Science Tohoku University
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