Reactions of 1-Azaazulan-2-one and Its 3-Substituted Derivatives

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概要

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• Chemical properties of l-azaazulan-2-one (I) and its 3-substituted derivatives such as 3-acetyl, 3-cycloheptatrienyl and 3-ethoxycarbonyl were investigated. It was shown that the electrophilic substitution reactions take place at the 3-position, replacement of the substituents occuring in some cases by the reactions with cationoid reagents. The Beckmann rearrangement, Curtius rearrangement, Hofmann degradation reaction, Stevens-McFadyen reaction, <I>etc.</I> of these compounds are described.

• 公益社団法人 日本化学会の論文

著者

• Toda Takashi

  Department Of Applied Chemistry Faculty Of Engineering Utsunomiya University

• Nozoe Tetsuo

  Department of Chemistry Faculty of Science Tohoku University

• Ryu Shoji

  Department of Chemistry, Faculty of Science, Tohoku University

• Hagiwara Yohichi

  Department of Chemistry, Faculty of Science, Tohoku University

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