Hindered internal rotation around the C-N bond in 1H-azepine derivatives as studied by the NMR techniques.

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概要

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• Thermodynamical parameters for the restricted rotation of seven title derivatives have been obtained by means of DNMR techniques. The results were explained in terms of a conjugation of the nitrogen atom in the seven-membered ring with the adjacent carbonyl carbon.

• 公益社団法人 日本化学会の論文

著者

• SATAKE Kyosuke

  Department of Chemistry, Graduate School of Natural Science and Technology, Okayama University

• Yokoyama Yukihiro

  Department Of Chemistry University Of Tsukuba

• Morosawa Shiro

  Department Of Chemistry Faculty Of Science Okayama University

• Okumoto Takashi

  Department Of Applied Electronics Tokyo University Of Science

• Kimura Masaru

  Department Of Anatcmy Aichi Medical University

• Takahashi Kensuke

  Department Of Applied Chemistry Nagoya Institute Of Technology

• Saito Katsuhiro

  Department Of Agricultural And Resource Economics The University Of Tokyo

• Takamuku Hiromi

  Department of Chemistry, Faculty of Science, Okayama University

• Itoh Shuji

  Department of Applied Chemistry, Nagoya Institute of Technology

• Itoh Shuji

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Yokoyama Yukihiro

  Department of Applied Chemistry, Nagoya Institute of Technology

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