Photolysis of Ethylene at 1634 Å and 1849 Å
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概要
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The photolysis of ethylene was carried out at room temperature at 1634 Å and 1849 Å. Products at both wavelengths were hydrogen, acetylene, ethane, <I>n</I>-butane and 1-butene. Product analysis and the radical scavenger technique indicate the primary processes to be as follows.<BR>(<U>Remark: Graphics omitted.</U>)<BR>The molecular elimination process in the primary processes varied with wavelengths, and was determined to be 47% and 53% at 1634 Å and 1849 Å, respectively. With reference to the percentage reported at other wavelengths, it is pointed out that molecular elimination is suppressed with the increase in excitation energy.
- 公益社団法人 日本化学会の論文
著者
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HARA Hiroshi
Department fo Bioscience and Chemistry, Faculty of Agriculture
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Tanaka Ikuzo
Department of Chemistry, Tokyo Institute of Technology
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