The formation and extraction equilibria of several manganese(II) .BETA.-diketonates and their trioctyl-phosphine oxide adducts.
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概要
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From the distribution ratio of manganese(II) between carbon tetrachloride containing various amounts of β-diketone (HA) and trioctylphosphine oxide (TOPO), and an aqueous 1 mol dm<SUP>−3</SUP> perchlorate solution at 25 °C, the formation constants for the aqueous chelates and the TOPO adducts of the MnA<SUB>2</SUB>, and the partition constants for the MnA<SUB>2</SUB> chelates were determined. The constants were then compared with those of other divalent metal ions.
- 公益社団法人 日本化学会の論文
著者
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Iwahori Shigehisa
Department Of Chemistry Science University Of Tokyo
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Sekine Tatsuya
Department Of Applied Chemistry Kanagawa Institute Of Technology
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Murai Ryokichi
Department Of Chemistry Science University Of Tokyo
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Takahashi Kazuhiko
Department Of Applied Chemistry Tokyo Institute Of Technology
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Sekine Tatsuya
Departemnt of Chemistry, Science University of Tokyo
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Takahashi Kazuhiko
Department of Chemistry, Science University of Tokyo
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