Adduct formation of the mixed copper(II) 2-thenoyltrifluoroacetonate-3-isopropyltropolonate chelate with tributyl phosphate in solvent-extraction systems containing these ligands.
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概要
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From the extraction data of copper(II) in a perchlorate solution into carbon tetrachloride containing 2-thenoyltrifluoroacetone (Htta), 3-isopropyltropolone (Hipt), and tributyl phosphate (tbp), the formation of an adduct mixed chelate, Cu(tta)(ipt)(tbp), together with the Cu(tta)<SUB>2</SUB>, Cu(tta)<SUB>2</SUB>(tbp), Cu(tta)(ipt), and Cu(ipt)<SUB>2</SUB> species, was concluded, and the formation constant of this adduct mixed chelate was calculated.
- 公益社団法人 日本化学会の論文
著者
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Sekine Tatsuya
Department Of Applied Chemistry Kanagawa Institute Of Technology
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Tosaka Teruyuki
Department of Chemistry, Science University of Tokyo
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Sekine Tatsuya
Departemnt of Chemistry, Science University of Tokyo
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