The solvent extraction of thallium(I) as a dibenzo-18-crown-6 complex with the picrate ion.
スポンサーリンク
概要
- 論文の詳細を見る
The solvent extraction of thallium(I) with dibenzo-18-crown-6 (DBC) as the picrate into chloroform and benzene was measured at 25 °C. The extraction was nearly the same as that of potassium(I) and much better than rubidium(I); this tendency was mainly attributed to the difference in the stability of the DBC complexes in the aqueous phase. Thallium(III) was extracted only poorly.
- 公益社団法人 日本化学会の論文
著者
-
HASEGAWA Yuko
Department of Bioresources Science, Faculty of Agriculture, Kochi University
-
Sekine Tatsuya
Departemnt of Chemistry, Science University of Tokyo
-
Wakabayashi Hiroji
Department of Chemistry, Science University of Tokyo
関連論文
- Solvent Extraction Equilibria and Kinetics of Gallium(III) with 2-Thenoyltrifluoroacetone in the Absence and Presence of Trioctylphosphine Oxide in Toluene
- SOLVENT EXTRACTION OF TERNARY METAL COMPLEXES WITH CATIONIC DYES AND CO-EXTRACTION OF LIGAND-DYE ION-PAIRS
- SOLVENT EXTRACTION OF MAGNESIUM(II) AND CALCIUM(II) WITH BENZOYLTRIFLUOROACETONE IN CARBON TETRACHLORIDE IN THE ABSENCE AND PRESENCE OF TETRAALKYL AMMONIUMS
- LIQUID-LIQUID PARTITION BEHAVIOR OF AMMONIA AND AMMONIUM ION BETWEEN HEXANE CONTAINING TRIOCTYLPHOSPHINE OXIDE AND AQUEOUS PERCHLORATE SOLUTIONS
- Effect of Carnosine and Related Compounds on the Inactivation of Human Cu, Zn-Superoxide Dismutase by Modification of Fructose and Glycolaldehyde(Food & Nutrition Science)
- Inactivation of Cu, Zn-Superoxide Dismutase by Intermediates of Maillard Reaction and Glycolytic Pathway and Some Sugars
- Trend of Stabilities of Adducts of 4, 4, 4-Trifluoro-1-(2-thienyl)-1, 3-butanedionates with Phenylpyridines over Lanthanoid Series
- Solvent Extraction of Iron(II) and Iron(III) as Anionic Thiocyanate Complexes with Tetrabutylammonium Ions into Chloroform
- Several Factors Influencing the Stability of Extracted Species in Synergistic Extraction of Lanthanide(III) with Pivaloyltrifluoroacetone and 2,2'-Bipyridyl
- Variation of Thermodynamic Parameters in the Adduct Formation of β-Diketonato Chelates with 1, 10-Phenanthroline across the Lanthanoid Series
- SOLVENT EXTRACTION EQUILIBRIA OF FIVE DIVALENT METAL IONS WITH DIBENZOYLMETHANE
- Effect of the Hydrophobic Anion of Picrate on the Extraction of Europium(III) with Diamide
- Solvent Extraction of Copper(I) and Copper(II) from Aqueous Halide Solutions with Tetrabutylammonium Ions into Chloroform
- SOLVENT EXTRACTION OF CADMIUM(II) FROM THIOCYANATE SOLUTIONS WITH METHYLISOBUTYLKETONE AND TRIOCTYLPHOSPHINE OXIDE IN HEXANE
- Rate and Equilibrium of the Distribution of 2-Thenoyltrifluoroacetone in Carbon Tetrachloride-Aqueous Perchlorate Solution Systems
- Variation of Formation Constants of Adducts of Lanthanoid(III) Chelates with Benzoic and Phenylacetic Acids across the Series
- Polarity Effect of Organic Solvents on the Separation Factors across the Lanthanoid Series
- Thermodynamic Consideration for Solvent Effects in the Synergistic Extraction of Europium(III) with Pivaloyltrifluoroacetone and 1,10-Phenanthroline
- On Compiling the Papers Presented in ITAS'94 as a Special Issue
- Water Molecules in Organic Solvents Involved in the Synergistic Extraction of Europium(III) with β-Diketones and Lewis Bases
- Branched-chain amino acid-enriched nutrients improve nutritional and metabolic abnormalities in the early post-transplant period after living donor liver transplantation
- On the extractability of univalent cation as dibenzo-18-crown-6 complexes with picrate ion.
- Mutual and Acid Distribution in Methyl Isobutyl Ketone-Water System
- Distribution of Aqueous Sodium Perchlorate into Some Polar Organic Solvents
- The stability constants of nickel(II) complexes with chloride, thiocyanate, sulfate, thiosulfate, and oxalate ions, as determined by a solvent extraction method.
- Extraction of nickel(II) in aqueous thiocyanate-perchlorate solutions with trioctylphosphine oxide in hexane and with 4-methyl-2-pentanone.
- The formation and extraction equilibria of several manganese(II) .BETA.-diketonates and their trioctyl-phosphine oxide adducts.
- Synergistic extraction of copper(II) and zinc(II) with tributyl phosphate and crown ether.
- The Distribution of 2-Thenoyltrifluoroacetone between Several Organic Solvents and an Aqueous Solution and Its Extraction of Sodium (I) into Methyl Isobutyl Ketone
- Adduct formation of the mixed copper(II) 2-thenoyltrifluoroacetonate-3-isopropyltropolonate chelate with tributyl phosphate in solvent-extraction systems containing these ligands.
- Studies of the Alkaline Earth Complexes in Various Solutions. V. Calcium(II) and Strontium(II) Complexes with Carbonate Ions in 1M Sodium Chloride Media
- Rate of solvent extraction of chromium(III) with acetylacetone into carbon tetrachloride.
- Solvent extraction of iron(III) in concentrated nitric acid with several .BETA.-diketones.
- Extraction of lead(II) in aqueous thiocyanate-perchlorate solutions wtih trioctylphosphine oxide in hexane and with 4-methyl-2-pentanone.
- Studies on the solvent extraction of metal perchlorates III. Extraction equilibria of alkaline earth ions with trioctylphosphine oxide as perchlorate and thiocyanate.
- Association of .BETA.-diketones with trioctylphosphine oxide in solvent extraction systems.
- Solvent extraction equilibria of acids. VI. The extraction of several mono- and dicarboxylic acids with trioctylphosphine oxide in hexane.
- Solvent extraction equilibria of thallium(III) from weakly acidic chloride solutions into 4-methyl-2-pentanone.
- The Solvent Extraction of Zinc(II) in Sodium Perchlorate-halide Solutions with Trioctylphosphine Oxide
- Rate of ligand exchange of tris(acetylacetonato)iron(III) with 2-thenoyltrifluoroacetone in organic solvents.
- Solvent extraction equilibria of acids. VII. The co-extraction of water with strong mineral acids by trioctylphosphine oxide.
- Effects of phenyl groups on thermodynamic parameters of lanthanoid(III) complexation with aromatic carboxylic acids.
- Lithium salt effects on extractions of 15-crown-5,18-crown-6, or their silver(I) complexes as picrates.
- A Study of Silver(I) Complexes with Some π-Donors and n-Donors in Chloroform by the Solvent Extraction Method
- Kinetic Studies of the Solvent Extraction of Metal Complexes. II. The Rate of the Extraction of Iron(III) with Thenoyltrifluoroacetone into Carbon Tetrachloride
- Kinetic Studies of the Solvent Extraction of Metal Complexes. I. The Extraction of the Beryllium(II)-TTA Chelate from Aqueous Perchlorate Media into Carbon Tetrachloride and Methyl Isobutyl Ketone
- Formation of Zinc(II) Complexes with Several Carboxylic Acids and Their Extraction with Carbon Tetrachloride
- The Solvent Extraction of Iron(III) in Perchlorate Solutions Containing Chloride or Bromide Ions with 2-Thenoyltrifluoroacetone and Trioctylphosphine Oxide
- The solvent extraction of thallium(I) as a dibenzo-18-crown-6 complex with the picrate ion.
- Studies on the solvent extraction of metal perchlorates. II. Extraction of alkali metal perchlorates with trioctylphosphine oxide.