Enantioselective Synthesis of Four Isomers of 3-Hydroxy-4-Methyltetradecanoic Acid, the Constituent of Antifungal Cyclodepsipeptides W493 A and B
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概要
- 論文の詳細を見る
Four possible stereoisomers of 3-hydroxy-4-methyltetradecanoic acid were enantioselectively synthesized by using Sharpless epoxidation and a subsequent epoxide-ring opening reaction with trimethylaluminum as the key steps. The absolute configuration of the β-oxyacid component of antifungal cyclodepsipeptides W493 A and B was consequently determined as 3S,4R.
- 社団法人 日本農芸化学会の論文
- 2005-01-23
著者
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宮入 一夫
Department Of Biochemistry And Biotechnology Faculty Of Agriculture And Life Science Hirosaki Univer
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Miyairi Kazuo
Faculty Of Agriculture Hirosaki University
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NIHEI Ken-ichi
Department of Biochemistry and Biotechnology, Faculty of Agriculture and Life Science, Hirosaki Univ
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HASHIMOTO Kimiko
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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MIYAIRI Kazuo
Department of Biochemistry and Biotechnology, Faculty of Agriculture and Life Science, Hirosaki Univ
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OKUNO Toshikatsu
Department of Biochemistry and Biotechnology, Faculty of Agriculture and Life Science, Hirosaki Univ
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Hashimoto K
Keio Univ. Yokohama Jpn
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Nihei Kenichi
Department Of Biochemistry And Biotechnology Faculty Of Agriculture And Life Science Hirosaki Univer
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Hashimoto Kimiko
Department Of Applied Chemistry Faculty Of Science And Technology Keio University
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Nihei Ken-ichi
Department Of Applied Biochemistry Faculty Of Agriculture Utsunomiya University
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Okuno T
Department Of Biochemistry And Biotechnology Faculty Of Agriculture And Life Science Hirosaki Univer
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Hashimoto Kensuke
Faculty Of Engineering Fukuyama University
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Okuno Toshikatsu
Department of Agricultural Chemistry, Faculty of Agriculture, Hirosaki University
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