Monohydroperoxides Formed by Autoxidation and Photosensitized Oxidation of Methyl Eicosapentaenoate
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概要
- 論文の詳細を見る
Methyl eicosapentaenoate (methyl 5, 8, 11, 14, 17-eicosapentaenoate) was subjected to autoxidation and methylene blue sensitized photooxidation. Methyl eicosapentaenoate monohydroperoxides, the primary products of the autoxidation and photosensitized oxidation, were isolated by silica gel column chromatography, and characterized by ultraviolet, infrared and nuclear magnetic resonance spectra. The isomeric composition of the monohydroperoxideswere determined by gas chromatography-mass spectrometry as follows : the 5-, 8-, 9-, 11-, 12-, 14-, 15- and 18-isomers (autoxidation), and the 5-, 6-, 8-, 9-, 11-, 12-, 14-, 15-, 17- and 18-isomers (photosensitized oxidation). Methyl eicosapentaenoate was readily oxidized both by autoxidation and by photosensitized oxidation.
- 社団法人 日本農芸化学会の論文
著者
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Yamauchi Ryo
Department Of Applied Life Science Faculty Of Applied Biological Sciences Gifu University
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Kato Koji
Department Of Applied Life Science Faculty Of Applied Biological Sciences Gifu University
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UENO Yoshimitsu
Department of Agricultural Chemistry, Faculty of Agriculture, Gifu University
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YAMADA Tomoo
Department of Agricultural Chemistry, Gifu University
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YAMAUCHI Ryo
Department of Agricultural Chemistry, Gifu University
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KATO Koji
Department of Agricultural Chemistry, Faculty of Agriculture, Gifu University
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