Catalytic Enantioselective Aziridination of Alkenes Using Chiral Dirhodium(II) Carboxylates
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概要
- 論文の詳細を見る
The enantioselective aziridination of alkenes with [N-(4-nitrophenylsulfonyl)imino]phenyliodinane catalyzed by dirhodium(II) tetrakis[N-tetrachlorophthaloyl-(S)-tert-leucinate], Rh2(S-TCPTTL)4, is described. While such enantioselectivities are highly dependent on the properties of the alkenes, 2,2-dimethylchromene was found to be a particularly suitable substrate which can be efficiently transformed into the aziridine product in 98% yield with 94% ee.
- The Japan Institute of Heterocyclic Chemistryの論文
- 2007-04-13
著者
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橋本 俊一
北大院薬
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TANAKA Masahiko
NIMS Beamline Station at Spring-8, National Institute for Materials Science
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Tanaka Masahiko
Nims Beamline Station At Spring-8 National Institute For Materials Science
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Tanaka Masahiko
National Institute For Materials Science
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Anada Masahiro
Graduate School Of Pharmaceutical Sciences Hokkaido University
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