3-2-2 スギの低温触媒ガス化による水素製造(3-02 ガス化1,Session 3 バイオマス等)

概要

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The influence of nickel catalyst on the tar evolution in the pyrolysis and the amount of hydrogen evolution in the steam gasification of Japanese cedar (hereafter referred to as Sugi) below 500℃ was examined in this study. The pyrolysis of Sugi without nickel catalyst produced 22.6 and 20.6 wt.% of char at 450 and 500℃, respectively. The char yield increased gradually with increasing the amount of nickel catalyst and reached 32.0 and 27.6 wt.% at 450 and 500℃ for the Sugi with 8.3 wt.% of nickel, respectively. The XRD showed that the nickel catalyst in the pyrolyzed char existed as a metallic state for all nickel-loaded samples and the crystallite size was small. The steam gasification of Sugi without nickel catalyst hardly occurred below 500℃. On the other hand, the char conversion for the Sugi with nickel catalyst drastically increased more than 95 wt.% at 500℃. And the amount of hydrogen evolution reached 130-140 mmol/g for all samples, which corresponded to the amount calculated from the carbon content in the pyrolyzed char.
2012-07-30