AF-like Ground State of Mn-DNA and Charge Transfer from Fe to Base-π-Band in Fe-DNA(Cross-disciplinary physics and related areas of science and technology)
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概要
- 論文の詳細を見る
The electronic states of M-DNA doped with M=Mg, Ca, Zn, Mn, Fe are investigated mainly with magnetic properties. In the "wet" condition the Mn ions of Mn-DNA form a 1-D chain in the center of a DNA double helix, as evidenced from the formation of the unnatural base pair combination with M, poly(dA)-M-poly(dC), but in the "dry" condition they form a 3-D network with the antiferromagnetic ground state around 0.4K with the superexchange coupling via water molecules. The valence of 3+ is found only in Fe-DNA, from which the base π-band obtains π charge carriers.
- 社団法人日本物理学会の論文
- 2007-04-15
著者
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SATO Hideyuki
Department of Physics, Tokyo Metropolitan University
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AOKI Yuji
Department of Physics, Tokyo Metropolitan University
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溝口 憲治
東京都立大学大学院理学研究科物理学専攻
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NAKAMURA Toshikazu
Institute for Molecular Science, Myodaiji
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Aoki Yuji
Department Of Physics Faculty Of Science:department Of Physics Faculty Of Science Tokyo Metropolitan
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Mizoguchi Kenji
Department of Physics, Tokyo Metropolitan University
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Aoki Yuji
Department Of Chemistry Faculty Of Science Gakushuin University
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Mizoguchi Kenji
Department Of Applied Physics School Of Engineering University Of Tokyo
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斯波 弘行
東京工大
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SAKAMOTO Hirokazu
Department of Physics, Tokyo Metropolitan University
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Sugawara Hitoshi
Faculty Of Integrated Arts And Science University Of Tokushima:graduate School Of Science Tokyo Metr
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Shiozawa Hidetsugu
Department Of Physics Tokyo Metropolitan University
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YONEZAWA Yuki
Department of Physics, Tokyo Metropolitan University
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Nakamura Toshikazu
Institute For Molecular Science
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Yonezawa Yuki
Department Of Physics Tokyo Metropolitan University
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Sakata H
Department Of Physics Tokyo Institute Of Technology
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TANAKA Shunsuke
Department of Physics, Tokyo Metropolitan University
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OJIMA Masaya
Department of Physics, Tokyo Metropolitan University
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SANO Sayaka
Department of Physics, Tokyo Metropolitan University
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NAGATAORI Mai
Department of Physics, Tokyo Metropolitan University
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FURUKAWA Kou
Institute for Molecular Science
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Sano Sayaka
Department Of Physics Tokyo Metropolitan University
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Nagataori Mai
Department Of Physics Tokyo Metropolitan University
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Ojima Masaya
Department Of Physics Tokyo Metropolitan University
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Sato Hideyuki
Department Of Cardiology Osaka University Graduate School Of Medicine
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Tanaka Shunsuke
Department Of Chemical Engineering Faculty Of Engineering Kansai University
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Tanaka Shunsuke
Department Of Physics Tokyo Metropolitan University
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Sakamoto Hirokazu
Department Of Internal Medicine Wakayama Rosai Hospital
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溝口 憲治
Department Of Physics Tokyo Metropolitan University
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Sato Hideyuki
Department Of Applied Chemistry Faculty Of Science And Technology Keio University
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Aoki Yuji
Graduate School Of Science Tokyo Metropolitan University
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溝口 憲治
Department of Physics, Tokyo Metropolitan University
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