A Useful Method for Deprotection of the Protective Allyl Group at the Anomeric Oxygen of Carbohydrate Moieties Using Tetrakis(triphenylphosphine)palladium
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概要
- 論文の詳細を見る
We have developed a simple method for the deprotection of allyl groups used as a protective group for the anomeric oxygen on a sugar moiety by employing tetrakis(triphenylphosphine) palladium in acetic acid. This method is applicable for not only simple but also complex allyl glycosides, such as natural lipid A intermediates and other important lipid A intermediates. Further, this method would be useful for large-scale preparation.
- 社団法人日本薬学会の論文
- 1992-07-25
著者
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東 邦雄
Drug Delivery System Institute Ltd.
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日馬 恒雄
Exploratory Research Laboratories I Daiichi Pharmaceutical Co. Ltd.
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中山 清
Exploratory Research Laboratories I, Daiichi Pharmaceutical Co. Ltd.,
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東 邦雄
Exploratory Research Laboratories I, Daiichi Pharmaceutical Co. Ltd.,
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曽我 恒彦
Exploratory Research Laboratories I, Daiichi Pharmaceutical Co. Ltd.,
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魚戸 浩一
Exploratory Research Laboratories I, Daiichi Pharmaceutical Co. Ltd.,
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中山 清
Exploratory Research Laboratories I Daiichi Pharmaceutical Co. Ltd.
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魚戸 浩一
Exploratory Research Laboratories I Daiichi Pharmaceutical Co. Ltd.
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曽我 恒彦
Exploratory Research Laboratories I Daiichi Pharmaceutical Co. Ltd.
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