A TOTAL AND PRACTICAL SYNTHESIS OF ERGOT ALKALOID, (±)-AURANTIOCLAVINE

スポンサーリンク

概要

論文の詳細を見る
The first synthesis of (±)-aurantioclavine by a convenient and practical five-step synthetic method, involving a new intra-molecular cyclization of nitro-olefin, is achieved starting from 3-formylindole with a 31% overall yield without using any protective groups.
1985-05-25

著者

関連論文

The Chemistry of Indoles. XLIV. : Synthetic Study Directed toward 3,4,5,6-Tetrahydro-1H-azepino[5,4,3-cd]indoles
A Novel Method for Attacking Non-activated C-H Bond and Its Application to the Synthesis of Gibberellin-A_ from Enmein
Purines. LX. Dimroth Rearrangement and Concomitant Hydrolytic Deamination of 7-Alkyl-1-methyladenines
A TOTAL AND PRACTICAL SYNTHESIS OF ERGOT ALKALOID, (±)-AURANTIOCLAVINE
62 麦角アルカロイド、(±)-clavicipitic acidの5工程全合成(ポスター発表の部)
THE CHEMISTRY OF 1-HYDROXYINDOLES : SYNTHESES OF METHYL 1-HYDROXYINDOLE-3-ACETATE, N__-B-ACETYL-1-HYDROXY-TRYPTAMINE, (±)- AND (S__-)-1-HYDROXYTRYPTOPHAN DERIVATIVES
A SIMPLE SYNTHESIS OF THE INDOLE ALKALOID BIPOLARAMIDE AND ITS DERIVATIVES
20 タリウムの化学を利用した新反応群の開拓とその天然物合成への応用(口頭発表の部)
TIN-THALL REACTION, A VERSATILE METHOD FOR CROSS COUPLING TIN COMPOUNDS WITH THALLIUM COMPOUNDS(Communication to the Editor)
The Chemistry of Indoles. XXXIII. : Substituent Effect in Regioselective Metalation of 3-Indolecarbaldehyde and Syntheses of Indoles Carrying a Carbon Side Chain at the 4-, 5-, 6-, or 7-Position
The Chemistry of Indoles. XXXII. : A Facile Synthetic Method for 6-Indolecarbaldehyde, 6-Indolemethanol, and 6-Substituted 1-Hydroxyindoles and Its Application for the Synthesis of a Natural Alkaloid, (E)-6-(3-Methylbuta-1,3-dienyl)indole
BORONATION-THALLATION, A NEW APPROACH TO THE SYNTHESIS OF INDOLES HAVING ARYL AND/OR A HETEROARYL SUBSTITUENT AT THE 4-POSITION
57 麦角アルカロイド全合成研究
SHORT-STEP SYNTHESIS OF THE ERGOT ALKALOIDS, (±)-NORCHANOCLAVINE-I, (±)-CHANOCLAVINE-I, (±)-ISOCHANOCLAVINE-I, AND (±)-AGROCLAVINE
The Chemistry of Indoles. XXVII. : A Practical Synthesis of the 1-Methoxy Analog of an Ergot Alkaloid, (±)-1-Methoxy-6,7-secoagroclavine
TOTAL SYNTHESIS OF (±)-PANICULIDINE B
The Chemistry of Indoles. XXIV. Syntheses of 3-Indoleacetic Acid and 3-Indoleacetonitrile Having a Halogeno Group and a Carbon Functional Group at the 4-Position
29 短工程かつ実用的な麦角アルカロイド全合成
A PRACTICAL SYNTHESIS OF THE ERGOT ALKALOID (±)-6,7-SECOAGROCLAVINE
The Chemistry of Indoles. XIII. Syntheses of Substituted Indoles carrying an Amino, Nitro, Methoxycarbonyl, or Benzyloxy Group at the 4-Position and Their 1-Hydroxy Derivatives
A NOVEL THREE-CARBON ANNELATION METHOD FOR PYRIDINE DERIVATIVES
Titanium (III) Chloride for the Reduction of Heteroaromatic and Aromatic Nitro Compounds
Cycloadditions in Syntheses. XXVI. : 1,2-Dihydrocyclobuta[b]-naphthalene-3,8-diones : Synthesis by Photochemical Means and Their Reactions via 2,3-Dimethylene-1,4-dioxo-1,2,3,4-tetrahydronaphthalenes
Studies on the N-Oxides of π-Deficient N-Heteroaromatics. XXXIV. A Novel Synthesis of Substituted Indoles by Photochemical Ring Contraction of 3,1-Benzoxazepines
Studies on the N-Oxides of π-Deficient N-Heteroaromatics. XXXVI. Photochemical and Thermal Michael Reactions of Alcohols with Methyl 2-Phenyl-3,1-benzoxazepine-5-carboxylate and Its Derivatives
A Novel Synthesis of Revenine and Related Alkaloids by Means of a Photo-rearrangement Reaction of 4-Alkoxy-2-methylquinoline 1-Oxides
SYNTHETIC STUDY DIRECTED TOWARD CYCLOPIAZONIC ACID
The Chemistry of Indoles. XII. A Facile Route to 5-Nitroisocoumarins and Methyl Indole-4-carboxylate

もっと見る

スポンサーリンク