A Kinetic Study of Formation of β-Arylaminoacrolein Derivatives from β-Ethoxyacrolein and Aromatic Primary Amines
スポンサーリンク
概要
- 論文の詳細を見る
Formation of β-arylaminoacrolein from β-ethoxyacrolein (I) and arylamine was studied kinetically. Hammett plot for second order rate constants gave a good linear line with ρ value of-2.63. Neither triethylamine nor acetic acid acted as an effective catalyst for the reaction. In the presence of acetic acid a remarkable amount of malonaldehyde dianil formed as a by-product. Reaction mechanism was discussed.
- 公益社団法人日本薬学会の論文
- 1979-02-25
著者
-
田村 眞造
School of Pharmaceutical Sciences, Toho University
-
田村 眞造
School Of Pharmaceutical Sciences Toho University
-
田村 真造
東邦大学 薬
-
武田 恵美子
School Of Pharmaceutical Science Toho University
関連論文
- A Kinetic Study of Cyclodehydration of β-(p-Toluidino)-acrolein. I
- Amidines. VIII. A Kinetic Study of Alcoholysis of N^1-Arenesulfonyl-N^1,N^2-diarylacetamidines
- Amidines. VII. : Hydrolysis and Alcoholysis of Carboxamides under Mild Conditions
- Amidines. VI. : 1,3-N, N-Acylotropic Amidine Rearrangement of N^1-Acyl Derivatives of N^1,N^2-Disubstituted Amidine
- Amidines. V. : Smiles Rearrangement of N^1-(p-Nitrobenzenesulfonyl)-N^1,N^2-diarylacetamidines
- Amidines. IV. : Hydrolysis of N^1-Acyl Derivatives of N^1,N^2-Diarylamidine in Carboxylate Buffer Solution
- Amidines. III. : A Kinetic Study of Acid Hydrolysis of Unsymmetrical N^1,N^2-Disubstituted Amidines
- Amidines.II. : Preparation of Unsymmetrical N^1,N^2-Disubstituted Amidines
- Amidines. I. Hydrolysis of N^1-Acyl- and N^1-Tosyl-N^1,N^2-diarylamidines
- A Kinetic Study of Alkaline Hydrolysis of 1-Arylamino-3-arylimino-1-butene
- A Kinetic Study of Alkaline Hydrolysis of β-Arylaminoacrolein
- A Kinetic Study of Cyclodehydration of β-Arylaminocroton-aldehyde Derivatives
- Preparation and Cyclodehydration of β-Arylaminocrotonaldehyde
- Preparation of 3-Substituted Quinolines. I. Alkylation of Malonaldehyde Dianil Derivatives
- Hydrolysis of Acyl Derivatives of N^1,N^2-Diarylamidine. I
- A Kinetic Study of Hydrolysis of β-Arylaminoacrolein Derivatives
- Reaction of β-Ethoxyacrolein and p-Toluidine in Benzene Solution
- Hydrolysis of Acyl Derivatives of Malonaldehyde Dianil. IV. Preparation of β-(p-Toluidino) crotonaldehyde
- Hydrolysis of Acyl Derivatives of Malonaldehyde Dianil. III
- Hydrolysis of Acyl Derivatives of Malonaldehyde Dianil. II. Aminolysis and Alcoholysis of Acyl Derivatives of Malonaldehyde Dianil and β-Arylaminoacrolein
- β-Arylaminoacrolein Derivatives. II. Cyclodehydration of β-Arylaminoacrolein Derivatives
- Hydrolysis of Acyl Derivatives of Malonaldehyde Dianil. I
- A Kinetic Study of Cyclodehydration of β-(p-Toluidino) acrolein. III
- A Kinetic Study of Cyclodehydration of β-(p-Toluidino) acrolein. II. Sulfonation of the Aromatic Ring as a Side Reaction of Cyclodehydration in Sulfuric Acid
- Hydrolysis of Malonaldehyde Dianil and β-Arylaminoacrolein Derivatives
- A Kinetic Study of Formation of β-Arylaminoacrolein Derivatives from β-Ethoxyacrolein and Aromatic Primary Amines
- Reaction of Heterocyclic Amino Compound with Malonaldehyde Derivatives