A Kinetic Study of Cyclodehydration of β-(p-Toluidino)-acrolein. I

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概要

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• The cyclodehydration of β-(p-toluidino)-acrolein (I) in sulfuric acid was studied kinetically in relation of that of 4-(p-toluidino)-3-penten-2-one (VII). Reversible sulfonation of I at α-position and cyclodehydration to 6-methylquinoline (II) proceeded in parallel. The difference in reactivity between β-arylaminoacrolein and 4-arylamino-3-penten-2-one was discussed.

• 社団法人日本薬学会の論文
• 1978-03-25

著者

• 伊東 和子

  Faculty Of Pharmaceutical Sciences Toho University

• 田村 眞造

  Faculty of Pharmaceutical Sciences, Toho University

• 今村 玲子

  Faculty of Pharmaceutical Sciences, Toho University

• 田村 眞造

  School of Pharmaceutical Sciences, Toho University

• 田村 眞造

  School Of Pharmaceutical Sciences Toho University

• 田村 真造

  東邦大学 薬

• 今村 玲子

  Faculty Of Pharmaceutical Sciences Toho University

関連論文

• A Kinetic Study of Cyclodehydration of β-(p-Toluidino)-acrolein. I
• Amidines. VIII. A Kinetic Study of Alcoholysis of N^1-Arenesulfonyl-N^1,N^2-diarylacetamidines
• Amidines. VII. : Hydrolysis and Alcoholysis of Carboxamides under Mild Conditions
• Amidines. VI. : 1,3-N, N-Acylotropic Amidine Rearrangement of N^1-Acyl Derivatives of N^1,N^2-Disubstituted Amidine
• Amidines. V. : Smiles Rearrangement of N^1-(p-Nitrobenzenesulfonyl)-N^1,N^2-diarylacetamidines
• Amidines. IV. : Hydrolysis of N^1-Acyl Derivatives of N^1,N^2-Diarylamidine in Carboxylate Buffer Solution
• Amidines. III. : A Kinetic Study of Acid Hydrolysis of Unsymmetrical N^1,N^2-Disubstituted Amidines
• Amidines.II. : Preparation of Unsymmetrical N^1,N^2-Disubstituted Amidines
• Amidines. I. Hydrolysis of N^1-Acyl- and N^1-Tosyl-N^1,N^2-diarylamidines
• A Kinetic Study of Alkaline Hydrolysis of 1-Arylamino-3-arylimino-1-butene
• A Kinetic Study of Alkaline Hydrolysis of β-Arylaminoacrolein
• A Kinetic Study of Cyclodehydration of β-Arylaminocroton-aldehyde Derivatives
• Preparation and Cyclodehydration of β-Arylaminocrotonaldehyde
• Preparation of 3-Substituted Quinolines. I. Alkylation of Malonaldehyde Dianil Derivatives
• Hydrolysis of Acyl Derivatives of N^1,N^2-Diarylamidine. I
• A Kinetic Study of Hydrolysis of β-Arylaminoacrolein Derivatives
• Reaction of β-Ethoxyacrolein and p-Toluidine in Benzene Solution
• Hydrolysis of Acyl Derivatives of Malonaldehyde Dianil. IV. Preparation of β-(p-Toluidino) crotonaldehyde
• Hydrolysis of Acyl Derivatives of Malonaldehyde Dianil. III
• Hydrolysis of Acyl Derivatives of Malonaldehyde Dianil. II. Aminolysis and Alcoholysis of Acyl Derivatives of Malonaldehyde Dianil and β-Arylaminoacrolein
• β-Arylaminoacrolein Derivatives. II. Cyclodehydration of β-Arylaminoacrolein Derivatives
• Hydrolysis of Acyl Derivatives of Malonaldehyde Dianil. I
• A Kinetic Study of Cyclodehydration of β-(p-Toluidino) acrolein. III
• A Kinetic Study of Cyclodehydration of β-(p-Toluidino) acrolein. II. Sulfonation of the Aromatic Ring as a Side Reaction of Cyclodehydration in Sulfuric Acid
• Hydrolysis of Malonaldehyde Dianil and β-Arylaminoacrolein Derivatives
• A Kinetic Study of Formation of β-Arylaminoacrolein Derivatives from β-Ethoxyacrolein and Aromatic Primary Amines
• Reaction of Heterocyclic Amino Compound with Malonaldehyde Derivatives

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