Catalytic Rearrangement of O, S-Dialkyl Dithiocarbonates to S, S-Dialkyl Dithiocarbonates. IV. Use of Boron Trifluoride Etherate as Catalyst
スポンサーリンク
概要
- 論文の詳細を見る
Migration of alkyl group from O to S in the reaction of O, S-dialkyl dithiocarbonates with boron trifluoride etherate was studied to elucidate the reaction mechanism on the basis of results from kinetics, crossover reaction, and products formed. It was worthy of note that dialkyl methyl sulfonium fluoroborates were formed in a fairly good yield in reactions with O-alkyl S-methyl dithiocarbonates (alkyl=benzyl and cholesteryl) with boron trifiuoride etherate. Formation mechanism of these by-products was investigated and discussed.
- 公益社団法人日本薬学会の論文
- 1978-12-25
著者
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原野 一誠
Faculty of Pharmaceutical Sciences, Kumamoto University
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原野 一誠
崇城大学薬学部
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小牧 敬司
Faculty of Pharmaceutical Sciences, Kyushu University
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川田 俊展
Faculty of Pharmaceutical Sciences, Kyushu University
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田口 胤三
Faculty of Pharmaceutical Sciences, Kyushu University
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田口 胤三
Faculty Of Pharmaceutical Sciences Kyushu University
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川田 俊展
Faculty Of Pharmaceutical Sciences Kyushu University:(present Address)research Laboratories Yoshitom
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小牧 敬司
Faculty Of Pharmaceutical Sciences Kyushu University:(present Address)fujisawa Pharmaceutical Indust
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