THE ROLE OF THROUGH-BOND INTERACTION IN THERMAL BEHAVIOR OF CAGE MOLECULES

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概要

• 論文の詳細を見る

• The cage triketone 2 revealed different reactivities toward the thermal condition according to the substituents : the cyclobutane ring cleavage for alkyl substituents and the decarbonylation for methoxycarbonyl ones. The X-ray crystallographic study for the derivative of 2b showed a significantly long (1.635 (7) Å) C (Ph)-C (Ph) σ bond. The reaction mechanisms are discussed in terms of frontier molecular orbital (FMO) theory combined with the results of molecular mechanics and semiempirical MNDO molecular calculations.

• 社団法人日本薬学会の論文
• 1983-07-25

著者

• 岡本 康

  Institute Of Synthetic Organic Chemistry Faculty Of Pharmaceutical Sciences Kyushu University 62

• 原野 一誠

  Faculty of Pharmaceutical Sciences, Kumamoto University

• 原野 一誠

  崇城大学薬学部

• 大沢 映二

  Department of Chemistory, Faculty of Science, Hokkaido University

• 岡本 康

  Faculty of Pharmaceutical Sciences, Kyushu University 62

• 安田 昌巳

  Faculty of Pharmaceutical Sciences, Kyushu University 62

• 兼松 顕

  Faculty of Pharmaceutical Sciences, Kyushu University 62

• 安田 昌己

  九州大学薬学部

• 兼松 顕

  九州大学薬学部

• 大沢 映二

  Department Of Chemistory Faculty Of Science Hokkaido University

• 大沢 映二

  Department Of Chemistry Faculty Of Science Hokkaido University

• 安田 昌巳

  Faculty Of Pharmaceutical Sciences Kyushu University 62

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