Lewis Acid Catalyzed [2σ+2σ] Cycloreversion Reaction of Strained Cage Ketones to Triquinane Skeletons : Kinetic Evidence for a Large Acceleration of the Reaction Owing to Stereoelectronic Requirement
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概要
- 論文の詳細を見る
Cookson's pentacyclic cage diketones substituted with an electron-donating group (1b-e) underwent a remarkably fast [2σ+2σ] cycloreversion reaction under various Lewis acid catalyzed conditions. The high reactivity of these cage ketones is discussed in terms of push-pull type interactions on the basis of large substituent effects and kinetic measurements.
- 社団法人日本薬学会の論文
- 1984-11-25
著者
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岡本 康
Institute Of Synthetic Organic Chemistry Faculty Of Pharmaceutical Sciences Kyushu University 62
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兼松 顕
Institute of Synthetic Organic Chemistry, Fuculty of Pharmaceutical Sciences, Kyushu University 62
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瀬ノ口 和彦
Institute of Synthetic Organic Chemistry, Faculty of Pharmaceutical Sciences, Kyushu University 62
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兼松 顕
九州大学薬学部
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兼松 顕
Institute Of Applied Organic Chemistry Faculty Of Engineering Nagoya University
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瀬ノ口 和彦
Institute Of Synthetic Organic Chemistry Faculty Of Pharmaceutical Sciences Kyushu University 62
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