フロンティア軌道論によるペリ環状反応の解析と有機合成化学への応用
スポンサーリンク
概要
- 論文の詳細を見る
A new concept of cyclic conjugation as a modification of the Huckel rule has proven to be useful as a general method of predicting thermal stabilities and electonic peoperties of unsaturated cyclic organic molecules. We have been applying this concept to the design of reagents such as p-benzoquinone and 1,4-dithins. Pericyclic syntheses are very valuable method for the high stereo-, regio-, and periselective controls, and they could provide a logical assembling of molecules, especially highly strained cage compounds which are available or not available for natural sources. These pericyclic reactions are discussed in terms of frontier molecular orbital theory.
- 公益社団法人日本薬学会の論文
- 1985-05-25
著者
関連論文
- Lewis Acid Catalyzed [2σ+2σ] Cycloreversion Reaction of Strained Cage Ketones to Triquinane Skeletons : Kinetic Evidence for a Large Acceleration of the Reaction Owing to Stereoelectronic Requirement
- THE ROLE OF THROUGH-BOND INTERACTION IN THERMAL BEHAVIOR OF CAGE MOLECULES
- 不飽和七員環鉄錯体とジクロルカルベンとの周選択的環状付加反応・鉄カルボニル基のマスキング効果と環化付加体の反応性(発表論文抄録(1983年))
- 「化学展'86Fukuoka」に参画して(薬学志向の学生を開拓する努力は十分であろうか)
- フロンティア軌道論によるペリ環状反応の解析と有機合成化学への応用
- フラン類の分子内Diels-Alder反応における分子設計