The Chemistry of Leucomycins. III. Structure and Stereochemistry of Leucomycin A_3
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概要
- 論文の詳細を見る
Leucomycin A_3 (I) was oxidized with active manganese dioxide to dehydroleucomycin A_3 (II) which was identical with magnamycin B. Acid treatment of I yielded demycarosylleucomycin A_3 (VII), which was converted to a triacetate showing mass spectrum M^+ (m/e 725), and this observation confirmed the structure of I. The diene system of I was assumed to have a trans-trans configuration on the basis of its NMR spectrum, and a full structure of I was proposed with stereochemistry.
- 公益社団法人日本薬学会の論文
- 1968-07-25
著者
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小倉 治夫
College of Pharmaceutical Sciences, Kitasato University
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大村 智
School Of Pharmaceutical Sciences Kitasato University And The Kitasato Institute
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大村 智
Kitasato University and The Kitasato Institute
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秦 藤樹
Kitasato Institute
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片桐 通子
Kitasato Institute
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秦 藤樹
The Kitasato Institute
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