Electron Spin Resonance Studies of Photo-sensitized Decomposition of Methyl Alcohol in the Presence of p-Benzoquinone.
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概要
- 論文の詳細を見る
Photo-sensitized decomposition of methyl alcohol in the presence of p-benzoquinone has been investigated by electron spin resonance method at a frozen state. Four kinds of ESR spectrum were distinguished ; these were CH_2OH, CHO, CH_3 and probably p-benzosemiquinone radical. Inspection of the developing pattern of these spectra has led to a result that CHO and CH_3 radicals are secondarily produced rather than photoprimarily. The methyl radical was found to be less stable compared with the other radicals. The decay of methyl radical was investigated and found to obey the second order rate law. Photo-sensitized decomposition of ethyl alcohol was investigated additionally.
- 社団法人日本薬学会の論文
- 1967-07-25
著者
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神谷 護
Shizuoka College of Pharmacy
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畑野 研一郎
Faculty of Pharmaceutical Sciences, Nagoya City University
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神谷 護
Division Of Environmental Health Sciences University Of Shizuoka
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畑野 研一郎
Faculty Of Pharmaceutical Sciences Nagoya City University
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畑野 研一郎
Division of Physicochemical Technology, Faculty of Pharmaceutical Sciences, University of Tokyo
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管 孝男
Division of Physicochemical Technology, Faculty of Pharmaceutical Sciences, University of Tokyo
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管 孝男
Faculty Of Pharmaceutical Sciences University Of Tokyo:(present Address)faculty Of Pharmaceutical Sc
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