Isomerization of Epoxides to Ketones by Pentacyanocobalt Complex
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概要
- 論文の詳細を見る
Interaction of pentacyanocobalt hydride, HCo (CN)_6^<3->, with epoxides such as propylene oxide, cyclohexene oxide, and styrene oxide has been investigated in aqueous solutions. While hydrogenation of epoxides to alcohols took place, it appeared to give way, to some extent, to isomerization to form ketones especially when excess alkali was added. This newly discovered isomerization reaction is assumed to take place via the interaction of epoxides with univalent pentacyanocobalt complex, Co(CN)_5^<4->, that is formed in alkaline solution according to HCo (CN)_5^<2->+OH^-→Co (CN)_5^<4->+H_2O.
- 公益社団法人日本薬学会の論文
- 1970-05-25
著者
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管 孝男
Faculty of Pharmaceutical Sciences, University of Tokyo
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管 孝男
Faculty Of Pharmaceutical Sciences University Of Tokyo:(present Address)faculty Of Pharmaceutical Sc
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管 孝男
Faculty Of Pharmaceutical Sciences The University Of Tokyo
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金 鐘潤
Faculty Of Pharmaceutical Sciences University Of Tokyo
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