Application of the Gas Chromatographic Pulse Technique to the Study of the Selective Hydrogenation of Aniline on Acid or Base Supported Metals of Group VIII
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概要
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The selectivity for the ring hydrogenation of aniline was investigated by the gas chromatographic pulse technique on the acid or base supported nickel, cobalt and iron catalyst respectively. Following results were obtained : 1) The selectivity for the ring hydrogenation was best on cobalt among three metals. 2) The calcium oxide supported catalyst generally suppressed the hydrogenolysis at the carbon-nitrogen bond giving rise to the efficient hydrogenation of the ring. 3) The silica-alumina support enhanced the formation of secondary amines. The selectivity was discussed on the basis of the interaction of amine with the surface and possible mechanism was presented.
- 社団法人日本薬学会の論文
- 1965-06-25
著者
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山本 晴彦
Faculty Of Pharmaceutical Sciences Hokkaido University
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管 孝男
Division of Physicochemical Technology, Faculty of Pharmaceutical Sciences, University of Tokyo
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小原 誠
Division Of Physicochemical Technology Faculty Of Pharmaceutical Sciences University Of Tokyo
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山本 晴彦
Division of Physicochemical Technology, Faculty of Pharmaceutical Sciences, University of Tokyo
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管 孝男
Faculty Of Pharmaceutical Sciences University Of Tokyo:(present Address)faculty Of Pharmaceutical Sc
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